Product ID:637654, DURSBAN PRO INSECTICIDE
MSDS Date:02/09/1995
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CLQJF

VAN WATERS AND ROGERS INC

6100 CARILLON POINT
KIRKLAND, WA 98033-7357
US

Emergency Phone: 800-424-9300

Info Phone: 425-889-3400/425-889-3617

Preparer: NOT PROVIDED

Cage: 0STM5

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

CHLOROPYRIFOS {O,O-DIETHYL O-(3,5,6-TRICHLORO-2-PYRIDYL)

CAS: 2921-88-2

RTECS: TF6300000

OSHA PEL 0.2 MG/M3

ACGIH TLV: 0.2 MG/M3

PROPRIETARY EMULSIFIER

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

PROPRIETARY SOLVENTS

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

PROPYLENE GLYCOL

CAS: 57-55-6

RTECS: TY2000000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

LD50 LC50 Mixture:ORAL RAT LD50: 623MG/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: MAY CAUSE SLIGHT EYE IRRITATION.
CORNEAL INJURY UNLIKELY. SKIN: PROLONGED EXPOSURE NOT LIKELY TO
CAUSE SIGNIFICANT IRRITATION. A SINGLE PROLONGED EXPOSURE IS NOT
LIKELY TO RESULT IN MATERIAL BEIN G ABSORBED THROUGH SKIN IN
HARMFUL AMOUNTS. INGESTION: SINGLE DOSE ORAL TOXICITY IS CONSIDERED
TO BE LOW. SMALL AMOUNTS ARE NOT LIKELY TO CAUSE INJURY; SWALLOWING
LARGE AMOUNTS MAY CAUSE INJURY. IF AS PIRATED (LIQUID ENTERS LUNG),
MAY CAUSE LUNG DAMAGE/ EVEN DEATH DUE TO CHEMICAL PNEUMONIA.
INHALATION: AT ROOM TEMPERATURE, VAPORS ARE MINIMAL. IF MATERIAL IS
HEATED OR MIST IS PRODUCED, CONCENTRATION S MAY BE ATTAINED THAT
MAY BE HAZARDOUS.
Explanation of Carcinogenicity:CHLORPYRIFOS AND OTHER TESTED COMPONENTS
DID NOT CAUSE CANCER IN LONG-TERM ANIMAL STUDIES.
Effects of Overexposure:HEADACHE, DIZZINESS, INCOORDINATION, MUSCLE
TWITCHING, TREMORS, NAUSEA, ABDOMINAL CRAMPS, DIARRHEA, SWEATING,
PINPOINT PUPILS, BLURRED VISION, SALIVATION, TEARING, TIGHTNESS IN
CHEST, EXCESSIVE URINAT ION, OR CONVULSIONS.
Medical Cond Aggravated by Exposure:NOT PROVIDED

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET MEDICAL
ATTENTION. SKIN: WASH EXPOSED AREAS WITH PLENTY OF SOAP AND WATER.
GET MEDICAL ATTENTION. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE
REUS E. INGESTION: CALL PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY. DO NOT INDUCE VOMITING. DO NOT PUT ANYTHING INTO THE
MOUTH OF AN UNCONSCIOUS PERSON. INHALATION: REMOVE PERSON TO FRESH
AIR AND IF N OT BREATHING GIVE ARTIFICIAL RESPIRATION, PERFERABLY
MOUTH-TO-MOUTH. GET MEDICAL ATTENTION.

Flash Point Method:SCC
Flash Point:=115.C, 239.F
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:USE POSITIVE-PRESSURE, SELF-CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:FOAM FIREEXTINGUISHING SYSTEM IS
PREFERRED BECAUSE UNCONTROLLED WATER CAN SPREAD POSSIBLE
CONTAMINATION. TOXIC IRRITATING GASES MAY BE FORMED UNDER FIRE
CONDITIONS.

Spill Release Procedures:WEAR LONG PANTS, LONG SLEEVED SHIRT, AND
IMPERVIOUS RUBBER GLOVES WHEN HANDLING CONCENTRATE AND CLEANING UP
SPILLS. ABSORB SPILLS WITH AN INERT ABSORBANT MATERIAL SUCH AS
HAZORB, ZORBALL, SAND, DIRT. SCOOP CONCENTRATED ABSORBANT MATERIAL
INTO CONTAINER. THOROUGHLY WASH BODY AREAS THAT COME INTO CONTACT
WITH THIS PRODUCT. FOR LARGER SPILLS, CONSULT DOWELANCO
(517-636-4400).
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:SEE LABEL. KEEP OUT OF REACH OF
CHILDREN. DO NOT SWALLOW. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. AVOID BREATHING VAPORS AND SPRAY MIST. HANDLE CONCENTRATE
IN VENTIALTED AREA. WASH THOROUGHLY WITH SOAP AND WATER AFTER
HANDLING AND BEFORE EATING OR SMOKING.
Other Precautions:KEEP AWAY FROM FOOD, FEEDSTUFFS AND WATER SUPPLIES.
FOR HEALTH AND SAFETY INFORMATION ON END-USE DILUTIONS OF UP TO 1%
DURSBAN INSECTICIDES, SEE HEALTH AND SAFETY FACT SHEET, FORM NO.
312-10-014, AVAI LABLE FROM DOWELANCO.

Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW
THE EXPOSURE GUIDELINES. WHEN RESPIRATORY PROTECTION IS REQUIRED,
USE AN APPROVED AIR-PURIFYING OR POSITIVE-PRESSURE SUPPLIED AIR
RESPIRATOR DEPENDING ON THE POTENTIAL AIRBORNE CONCENTRATION.
Ventilation:PROVIDE GENERAL AND/OR LOCAL EXHAUST VENTILATION TO CONTROL
AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES.
Protective Gloves:CHEMICALLY-RESISTANT GLOVES
Eye Protection:SAFETY GLASSES
Other Protective Equipment:WEAR PROTECTIVE CLOTHING WHEN USING OR
HANDLING THIS PRODUCT TO HELP REDUCE EXPOSURE TO EYES AND SKIN.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K =
UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED.

HCC:T4
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:NOT DETERMINED
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:=130.C, 266.F
Vapor Pres:NOT DETERMINED
Vapor Density:N/D
Spec Gravity:1.07@20C
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:EMULSIFIABLE
Appearance and Odor:SLIGHTLY CLOUDY, COLORLESS LIQUID; ODOR:
INFORMATION NOT AVAILABLE.
Percent Volatiles by Volume:NOT PROVIDED
Corrosion Rate:NOT PROVIDED

OXIDIZING MATERIALS AND STRONG ACIDS. ORGANIC MATERIAL AND FINELY
DIVIDED INORGANIC MATERIALS SUCH AS CLAY, ROCK WOOL INSULATION,
RAGS, PAPER
Stability Condition to Avoid:AVOID HEATING ABOVE 50 C(122F).
Hazardous Decomposition Products:NITROGEN OXIDES, HYDROGEN CHLORIDE,
OTHER TOXIC IRRITATING VAPORS MAY BE FORMED IF PRODUCT IS INVOLVED
IN FIRES.

Waste Disposal Methods:DO NOT CONTAMINATE FOOD, WATER, FEED BY STORAGE
OR DISPOSAL. EXCESS PESTICIDE RESULTING FROM THE USE OF THIS
PRODUCT MAY BE DISPOSED OF ACCORDING TO LABEL DIRECTIONS OR AT AN
APPROVED WASTE DISPOSAL F ACILITY. FOLLOW ALL LOCAL, STATE AND
FEDERAL REQUIREMENTS FOR DISPOSAL.

Toxicological Information:LD50 FOR SKIN ABSORPTION IN RABBITS IS
GREATER THAN 2000 MG/KG.THE ORAL LD50 FOR MALE RATS WAS 632 MG/KG.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT PROVIDED

Transport Information:NOT PROVIDED

SARA Title III Information:SARA HAZARD CATEGORY: AN IMMEDIATE HEALTH
HAZARD, A DELAYED HEALTH HAZARD.
Federal Regulatory Information:TOXIC SUBSTANCES CONTROL ACT (TSCA): ALL
INGREDIENTS ARE ON THE TSCA INVENTORY OR ARE NOT REQUIRED TO BE
LISTED ON THE TSCA INVENTORY.
State Regulatory Information:1,2-PROPANEDIOL 57-55-6 IS CITED IN
PENNSYLVANIA HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR EQUAL
TO 1.0%). CHLORPYRIFOS, CAS# 2921-88-2 IS CITED IN PENNSYLVANIA
HAZARDOUS SUBSTANCE (PRESENT AT G REATER THAN OR EQUAL TO 1.0%),
NEW JERSEY HAZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR EQUAL TO
1.0%) AND PENNSYLVANIA ENVIRONMENTAL HAZARDOUS SUBSTANCE (PRESENT
AT GREATER THAN OR EQUAL TO 1.0%).